Well, I may have missed something. Having to reinstall anyway, this time I'll record while doing it and see if that'll help.
Edit: Reinstall due to messing with system32.dll. Had to use system restore and forgot to make a point between everything setup and messing with .dll files. Lost steam in the restore. hehe
Edit 2: Well darn. I had it recording, but twitch.tv didn't get my video. And now I can't get it to crash. Even dumping steam and bringing it back won't (un)fix it.
But here are the steps I did:
Go through setup. On first play through, it'll state the window is not responding. The crash dialog will come up. Instead of sending an error report close the Error Report & email window. This will close all associated windows.
Start it up again and wait for it a little bit. Eventually a dialog window will come up asking if you wish to (buttons) Start Simulation | Start Normally.
Pick: Start Simulation. Starting up is now fixed. Go into config (upper right circle with 3 dots), choose exit.
It will crash on exit, choose not to send an error report by closing it like before. Now exiting won't crash anymore in the future. Alternatively, you may close these by opening task manager and killing the process.
Choosing "Start Normally" or sending in Error Reports causes these alternate dialogs to not show up and causes the next sequence to crash the next time you run the program. I don't know why, but those are the results I got.